期刊
ORGANIC LETTERS
卷 15, 期 6, 页码 1166-1169出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4001087
关键词
-
资金
- National Research Foundation
- Korean government [NRF-2010-0009458, NRF-2012-015662]
The first gold-catalyzed Intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted beta-alkoxyacrylates in a highly efficient manner.
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