期刊
ORGANIC LETTERS
卷 15, 期 24, 页码 6140-6143出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403011r
关键词
-
资金
- NSF of China [20932003, 21125209]
- MOST of China [2011CB808600]
- STCSM [12JC1403800]
- Shanghai Postdoctoral Scientific Program [13R21412800]
An iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and beta,gamma-unsaturated alpha-keto esters is reported. The use of iron porphyrin catalyst allows aliphatic amines to be used as the substrate without encountering catalyst poisoning issue and a series of beta-hydroxy-alpha-amino esters are produced in high yields with excellent regioselectivities.
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