期刊
ORGANIC LETTERS
卷 15, 期 13, 页码 3404-3407出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401456h
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [22350058, 23655173]
- Sumitomo Chemical Co., Ltd.
- Nissan Chemical Industries, Ltd.
- Grants-in-Aid for Scientific Research [25109518, 25288033, 22350058, 23655173] Funding Source: KAKEN
Catenation of stable 1,3-diphopsphacyclobutane-2,4-diyl units with biphenyl-, diphenyl ether-, and diphenylmethane-based bridging groups were utilized for evaluation of the distinct through-space interaction between the electron-donating P-heterocyclic biradical chromophores. Structural properties of the oligo(biradicals), characterized by X-ray crystallography and DFT calculation, suggest a possible distance between the biradical units for the through-space interaction.
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