期刊
ORGANIC LETTERS
卷 14, 期 7, 页码 1780-1783出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3003699
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-
资金
- Institute of Bioengineering and Nanotcchnology (IBN) (Biomedical Research Council, Agency for Science, Technology and Research, Singapore)
A simple protocol for the stereoselective copper-catalyzed hydrothiolation of alkynes under a CO2 atmosphere has been developed. The stereoselectivity is determined by the presence/absence of a CO2 atmosphere. The reaction system is robust and utilizes inexpensive, readily available substrates. A cyclic alkene/carboxylate copper complex intermediate is proposed as the key step in determining the stereoselectivity, and an equivalent amount of water is found to play an active role as a proton donor.
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