期刊
ORGANIC LETTERS
卷 14, 期 19, 页码 5046-5049出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302273r
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资金
- National Institutes of Health [GM53386]
An enantioselective synthesis of (+)-lithospermic acid, a potent anti-HIV agent, has been accomplished in a convergent manner in nine steps. The synthesis features an enantioselective intramolecular oxa-Michael addition catalyzed by a quinidine derivative, a hypervalent iodine-mediated rearrangement of chromanone to dihydrobenzofuran, an enantioselective alpha-oxyamination, and an intermolecular C-H olefination.
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