期刊
ORGANIC LETTERS
卷 14, 期 3, 页码 808-811出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol203344c
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22550160]
- Matching Fund Subsidy for a Private University
- Grants-in-Aid for Scientific Research [24106741, 22550160, 10J07627] Funding Source: KAKEN
Fucoxanthin exhibits high energy transfer efficiencies to Chlorophyll a (Chl a) in photosynthesis in the sea. In order to reveal how each characteristic functional group, such as the length of the polyene chain, allene, and conjugated carbonyl groups, of this marine natural product are responsible for its remarkably efficient ability, the total synthesis of fucoxanthin by controlling the stereochemistry was achieved. The method established for fucoxanthin synthesis was successfully applied to the synthesis of the C42 longer chain analogue.
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