期刊
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卷 14, 期 7, 页码 1930-1933出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol300627p
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资金
- Austrian Science Foundation (FWF) [P21202-N17]
- Austrian Science Fund (FWF) [P 21202] Funding Source: researchfish
- Austrian Science Fund (FWF) [P21202] Funding Source: Austrian Science Fund (FWF)
A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylboronates. Substitution of the pyridine directing group in the 3-position proved to be crucial in order to achieve high arylation yields. Furthermore, the pyridine directing group can be removed in high yields via a two-step protocol.
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