期刊
ORGANIC LETTERS
卷 14, 期 12, 页码 3100-3103出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301192s
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资金
- Daiichi-Sankyo
- Grants-in-Aid for Scientific Research [23790016] Funding Source: KAKEN
Highly efficient palladium-catalyzed carbonylation of aryl, alkenyl, and allyl halides with phenyl formate is reported. This procedure does not use carbon monoxide and affords one-carbon-elongated carboxylic acid phenyl esters in excellent yields. The reaction proceeds smoothly under mild conditions and tolerates a wide range of functional groups including aldehyde, ether, ketone, ester, and cyano groups. Furthermore, a variety of heteroaromatic bromides can be converted to the corresponding phenyl esters in high yields.
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