期刊
ORGANIC LETTERS
卷 14, 期 3, 页码 950-953出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3000316
关键词
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资金
- MEXT [21750049]
- Otsuka Pharmaceutical Co., Japan
- Grants-in-Aid for Scientific Research [24750045, 21750049, 20350021] Funding Source: KAKEN
Direct allylation of inert amide carbonyls utilizing the Schwartz reagent afforded either substituted tertiary or secondary amines. A preactivation step was successfully avoided, which is generally a requisite to increase the electrophilicity of amides. The reaction exhibited remarkable functional group tolerance and proceeded even in the presence of methyl esters and nitro groups.
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