期刊
ORGANIC LETTERS
卷 14, 期 19, 页码 5134-5137出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302430h
关键词
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资金
- National Natural Science Foundation of China [21021001, 21172151]
- Ministry of Education [20110181130014]
- National Basic Research Program of China (973 Program) [2010CB833300]
The first catalytic enantioselective 1,2-reduction of enones with 0.45 mol equiv potassium borohydride solution catalyzed by a chiral N,N'-dioxide-Sc(III) complex catalyst was accomplished under mild reaction conditions. A number of optically active allylic alcohols were obtained in good to excellent enantioselectivities (up to 95% ee) with nearly quantitative yields.
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