期刊
ORGANIC LETTERS
卷 14, 期 18, 页码 4870-4873出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3021995
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资金
- DST-New Delhi
- CSIR
Indeno[2,1-b]thiophene and indeno[1,2-b]indole motifs have been obtained in moderate to good yields from easily available substituted boronic acids, 2-bromo aryl/vinyl aldehydes, and nucleophiles such as arenes/heteroarenes and others using a catalytic combination of bimetallic Pd-Sn and AgPF6. This formal three-component coupling involves a Suzuki reaction followed by nucleophile assisted tandem ring closure. The sequential synthesis of substituted heterocycle-fused indenes, benzofluorene, and fluorenes was also accomplished.
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