期刊
ORGANIC LETTERS
卷 14, 期 13, 页码 3340-3343出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3013167
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资金
- Indiana University
The reduction of a palladium enolate prior to beta-hydride elimination provides a unique reaction for the synthesis of the hydroazulene ring system. When combined with a transannular epoxide rearrangement cascade, the reductive-Heck reaction allows rapid entry to the oxo-bridged guaiane core of the englerins.
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