Carbocyclization Cascades of Ally! Ketenimines via Aza-Claisen Rearrangements of N-Phosphoryl-N-allyl-ynamides

A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein-Wagner rearrangements and polyene-type cyclizations en route to fused bi- and tricyclic frameworks are featured.