期刊
ORGANIC LETTERS
卷 13, 期 19, 页码 5052-5055出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol201882v
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-
资金
- National Institute of General Medical Sciences [G032134]
A novel triptycene-based ligand with a preorganized framework was designed to model carboxylate-bridged diiron active sites in bacterial multicomponent monooxygenase (BMM) hydroxylase enzymes. The synthesis of the bis(benzoxazole)-appended ligand L1 depicted was accomplished in 11 steps. Reaction of L1 with iron(II) triflate and a carboxylate source afforded the desired diiron(II) complex [Fe(2)L1(mu-OH)(mu-O2CArTol)(OTF)(2)].
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