期刊
ORGANIC LETTERS
卷 13, 期 23, 页码 6316-6319出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2028702
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资金
- NIH [R01 GM078240]
- Dainippon Sumitomo Pharma Co., Ltd.
Tartaric acid catalyzes the asymmetric addition of vinylboronates to N-acyl quinoliniums, affording highly enantioenriched dihydroquinolines. The catalyst serves to activate the boronate through a ligand-exchange reaction and generates the N-acyl quinolinium in situ from the stable quinoline-derived N,O-acetal.
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