期刊
ORGANIC LETTERS
卷 13, 期 18, 页码 4958-4961出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2020847
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资金
- Welch Foundation [E-1744]
- University of Houston
An enantioselective addition of alkenylboronic acids and alkynylboronic esters to unprotected indole-appended enones is reported. This transformation proceeds with high enantioselectivity and high product yields via the use of catalytic amounts of 3,3'-bis(pentafluorophenyl)-BINOL and Mg(Ot-Bu)(2). A range of a-branched indole derivatives are available from the transformation.
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