期刊
ORGANIC LETTERS
卷 13, 期 23, 页码 6304-6307出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2028515
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资金
- National Institutes of Health [GM54161]
Cyclocarbonylation of alpha-methylene butyrolactone-containing allene-ynes affords 6,12-guaianolide ring systems. Incorporation of the a-methylene butyrolactone early in a synthetic sequence is rare for reactivity reasons; however, this moiety proves to be beneficial to the allenic Pauson-Khand reaction. The three double bonds and the ketone in the resulting 5-7-5 ring system bear significant differences in their reactivity and are ideally positioned for synthetic application to 6,12-guaianolides and analogs.
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