期刊
ORGANIC LETTERS
卷 13, 期 14, 页码 3560-3563出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200957y
关键词
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资金
- MEXT [22105005, 22106520, 23685019]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [22106520, 22105005, 23685019] Funding Source: KAKEN
One molecule of acrylate reacts with two molecules of isocyanate in the presence of a nickel(0)/SIPr catalyst to give a 1,3,5-trisubstituted hydantoin. Two processes operate in sequence, the first, regioselective formation of N-substituted fumaramate from acrylate and isocyanate and, the second, ring closure of the fumaramate with incorporation of another molecule of isocyanate.
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