期刊
ORGANIC LETTERS
卷 13, 期 15, 页码 3810-3813出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2012633
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资金
- Duke University
The first asymmetric organocatalytic sulfenylation of in situ derived nitrosoalkenes leading to chiral nonracemic alpha-sulfenylated ketones is described. The transformation proceeds in an umpolung fashion, relative to enolate/azaenolate methods, and uses simple thiols, thereby obviating the need for electrophilic sulfur reagents.
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