期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 3114-3117出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2010227
关键词
-
资金
- NIH [GM066055]
A new approach to Oppolzer's Intramolecular Dlels-Alder cycloaddition (IMDA) through gamma-isomerlzation of readily available N-tethered allenamides is described. These IMDA reactions are carried out in tandem with the allenamide isomerization or 1,3-H shift, leading to complex nitrogen heterocycles in a highly stereoselective manner.
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