4.8 Article

Encapsulation of Tetrathiafulvalene Inside a Dimeric Molecular Capsule

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ORGANIC LETTERS
卷 13, 期 7, 页码 1770-1773

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AMER CHEMICAL SOC
DOI: 10.1021/ol200258g

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  1. National Science Foundation [CHE-848637]
  2. Division Of Chemistry
  3. Direct For Mathematical & Physical Scien [0848637] Funding Source: National Science Foundation

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Tetrathiafulvalene (TTF) is trapped inside a dimeric capsule formed by two octaacid, deep-cavity cavitands in aqueous solution. While the first one-electron oxidation of TTF is strongly hindered by encapsulation, the capsular assembly is eventually destabilized upon oxidation of the guest.

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