期刊
ORGANIC LETTERS
卷 13, 期 12, 页码 3036-3039出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol200878w
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资金
- CATAS-ITBB [110301]
- Natural Science Foundation of Yunnan [2008CD159]
Volvalerelactones A and B (1 and 2), two new sesquiterpenoid lactones with an unprecedented 317/6 tricyclic ring system, were isolated horn the roots of Valerlana officinal's var. latifolia. Their structures and relative configurations were elucidated by spectroscopic data and single-crystal X-ray diffraction crystallography, and the absolute configuration was assigned by computational methods. The possible biosynthetic pathways of 1 and 2 were also proposed.
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