期刊
ORGANIC LETTERS
卷 12, 期 19, 页码 4344-4347出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101789g
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-
资金
- National Institutes of Health [GM038436, 1 F31 GM087953-01]
The enantioselective synthesis of (Z)-1,2-anti-2,5-anti-triol monosilyl ethers via a two-step sequence involving olefin cross-metathesis of beta-alkoxyallylboronate 4 and subsequent allylboration of the derived bisboryl intermediate 6 provides triol monoethers 7 with good to excellent diastereoselectivity.
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