期刊
ORGANIC LETTERS
卷 12, 期 15, 页码 3308-3311出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101082v
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资金
- NSF [CHE-0844602]
- DOE [DE-FC26-04NT42136]
- [ACS-PRF-47843-G1]
- Direct For Mathematical & Physical Scien [0844602] Funding Source: National Science Foundation
- Division Of Chemistry [0844602] Funding Source: National Science Foundation
The FeCl(3)-catalyzed triazole propargylation was developed. This transformation was suitable for a large scope of substituted propargyl alcohols, giving the corresponding propargyl triazoles In excellent yields (up to 96%). Further derivatization produced the 1,1-bis-triazoles in excellent yields and regioselectivity, which could be applied as potential transition metal ligands or new reagents.
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