期刊
ORGANIC LETTERS
卷 12, 期 24, 页码 5616-5619出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102254q
关键词
-
资金
- European Commision [FP7-201431]
- PolyU Internal Grant DA (A-PDOX)
An effective organocatalytic asymmetric aldol reaction of acetone to beta,gamma-unsaturated alpha-keto ester has been developed. In the presence of 5 mol % of 9-amino (9-deoxy)-epicinchona alkaloid and 10 mol A of 4-nitrobenzoic acid, the aldol adducts containing a chiral tertiary alcohol moiety were obtained in excellent yields and enantioselectivities.
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