期刊
ORGANIC LETTERS
卷 12, 期 11, 页码 2614-2617出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol1008203
关键词
-
资金
- National Institute of General Medical Sciences [GM60567]
Progress toward a highly convergent, asymmetric synthesis of brevenal is reported. Construction of the AB-ring and E-ring cyclic ether fragments was achieved through asymmetric alkylation/ring-closing metathesis strategies. A Horner-Wadsworth-Emmons olefination was used in a key bond-forming step to couple the advanced cyclic fragments and enable rapid access to the AB-E ring system.
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