期刊
ORGANIC LETTERS
卷 12, 期 23, 页码 5558-5560出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102447s
关键词
-
资金
- National Institutes of Health [GM-64444]
An efficient palladium-catalyzed intramolecular carbopalladation/cyclization cascade toward tetra- and pentacyclic N-fused heterocycles has been developed. This transformation proceeds via the palladium-catalyzed coupling of aryl halides with internal propargylic esters or ethers followed by the 5-endo-dig cyclization leading to polycyclic pyrroloheterocycles in moderate to excellent yields.
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