期刊
ORGANIC LETTERS
卷 12, 期 9, 页码 1984-1987出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100453x
关键词
-
资金
- European Research Council (ERC)
- Fonds der Chemischen Industrie (FCI)
- DFG [SFB749]
The strong directing ability of the N,N,N',N'-tetramethyldiaminophosphorodiamidate group has been used to achieve selective metalations on various heterocycles such as pyridines, quinolines and quinoxalines with TMP-derived bases like TMPMgCl.LiCl, TMP2Mg.2LiCl, and TMP2Zn.2MgCl(2).2LiCl. This protocol was applied in the synthesis of etoricoxib, talnetant and a P-selectin inhibitor.
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