期刊
ORGANIC LETTERS
卷 12, 期 2, 页码 244-247出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902551m
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资金
- NNSFC [20872015]
- Science Foundation for Young Teachers of NENU [20090404]
- Young Scientific Research Foundation of Jilin Province [20090149]
A new concept, polarity-reversible conjugate addition, has been described, based on the findings that the polarity of a classical Michael acceptor can be reversed through remote electronic effects. In addition, the remote electronic effects are tunable, and both five- and six-membered nitrogen rings can be constructed starting from acyclic precursors having the same enone structure unit simply by varying a remote substituent in the molecules.
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