期刊
ORGANIC LETTERS
卷 12, 期 19, 页码 4416-4419出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101961c
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资金
- National Institute of General Medical Sciences [GM60567]
The enantioselective total synthesis of spirofungins A (1) and B (2) is reported in 14 steps over the longest linear sequence. Key steps include the use of thiazolidinethione-mediated aldol reactions to assemble the major fragments and installation of the C1-C6 side chain using a cross metathesis reaction.
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