期刊
ORGANIC LETTERS
卷 11, 期 12, 页码 2575-2578出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900874z
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资金
- ACS-PRF [45433-AC1]
A novel route to the synthesis of diarylmethanes via a Pd-catalyzed alpha-arylation of benzyl ketones is reported. By harnessing the inherent reactivity of enolates, it is possible to circumvent the need for a transmetalating reagent such as boron for the coupling. Additionally, the two phenyl rings of the intermediate are exploited to stabilize the high-energy carbanionic leaving group in a straightforward synthesis.
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