期刊
ORGANIC LETTERS
卷 11, 期 17, 页码 3890-3893出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901497t
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [471]
Bisarylindenones and an acetal derivative, a novel thermally Irreversible photochromic family based on 6 pi-electrocyclization with three easily modifiable functional groups, have been synthesized. 2,3-Bis(5-methyl-2-phenyl-4-thiazolyl)indenone showed photochromic back-and-forth reactions with two different visible lights. Its ethylene acetal recorded 0.81 as the photocyclization quantum yield in hexane, which is the largest value known to date for 6 pi-electrocyclization In solution.
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