期刊
ORGANIC LETTERS
卷 11, 期 13, 页码 2772-2774出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9009305
关键词
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资金
- NNSFC [20632010, 20772004, 20821062]
- MOST [2006CB806201]
Cage-opened fullerenes with 18-membered-ring orifices have been prepared starting from fullerene-mixed peroxides. The key transformation involves a cascade sequence including a deketalization, a S(N)2' epoxide opening reaction, and a formal 3,3-sigma rearrangement. The 18-membered-ring orifice is big enough for water encapsulation under mild conditions. Single crystal X-ray structures were obtained for both the empty and water-encapsulated fullerene derivatives.
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