4.8 Article

A Polyanionic Dendritic Fluorophore for Selective Detection of Hg2+ in Triton X-100 Aqueous Media

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ORGANIC LETTERS
卷 11, 期 13, 页码 2768-2771

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AMER CHEMICAL SOC
DOI: 10.1021/ol900929g

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  1. Thailand Research Fund (TRF)
  2. 90th Anniversary of Chulalongkorn University Fund (Ratchadaphiseksomphot Endowment Fund)

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A series of water-soluble fluorescent dendritic compounds composed of phenylene-ethynylene repeating units and anionic carboxylate or cationic ammonium peripheral groups were synthesized. The first generation fluorescent dendrimer containing nine phenylene-ethynylene units and six carboxylate peripheral groups exhibited a highly selective fluorescence quenching by Hg2+ ions. The Stern-Volmer constant (K-sv) was 33,700 M-1 in aqueous media in the presence of Triton X-100 surfactant.

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