期刊
ORGANIC LETTERS
卷 11, 期 16, 页码 3762-3765出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901429g
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- Ministero dell' Istruzione
- Ministero dell' Istruzione, dell'Universita e della Ricerca
A mild ring opening of vinyl epoxides and aziridines with B(2)Pin(2) catalyzed by Ni(O)-Binap affords new functionalized allylic boron derivatives which undergo sequential transformations. The uncatalyzed allylation of aldehydes allows obtaining challenging bishomoallylic alicyclic 1,3-diols and 1,3-amino alcohols with remarkably high stereoselectivities. Valuable trans-bisallylic 1,4-amino alcohols can be obtained by a simple oxidation.
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