期刊
ORGANIC LETTERS
卷 11, 期 15, 页码 3334-3337出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901183h
关键词
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资金
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
- Bayer Schering Pharma AG
Intramolecular samarium diiodide-induced carbonyl-alkene or carbonyl-alkyne coupling reactions afforded without high dilution conditions 9- and 10-membered benzannulated carbocycles of type II and III in surprisingly good yields and stereoselectivities. A novel samarium diiodide-mediated cascade process leading to tricyclic compounds of type IV was also observed. Bisbenzannulated 10- and 11-membered carbocycles were prepared in very good yields.
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