期刊
ORGANIC LETTERS
卷 11, 期 4, 页码 971-974出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802927v
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资金
- University of Kansas Center for Environmentally Beneficial Catalysis [EEC-0310689]
- National Institute of General Medical Sciences [1R01GM079644]
A robust and practical polymer-supported, recyclable biphephos rhodium(I) catalyst has been developed. Control of polymer molecular weight allowed the tuning of solubility such that the polymer-supported catalyst is soluble in nonpolar solvents and not soluble in polar solvents. Thus, catalytic addition of aryl- and vinylboronic acids to enones occurs under completely homogeneous conditions and catalyst recycle can be achieved by simple precipitation and filtration.
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