期刊
ORGANIC LETTERS
卷 11, 期 2, 页码 425-428出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802412b
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资金
- National Institute of General Medical Sciences of the National Institutes of Health [GM-54909]
- National Institutes of Health [GM-57688]
- Amgen and Lilly
The copper-catalyzed insertions of nitriles into the Si-C bonds of silacyclopropenes provide azasilacyclopentadienes, which can be converted to allylic amines after reduction and protodesilylation. The enamine functionality of azasilacyclopentadienes also participates in 1,4-addition reactions and undergoes a hydroboration and oxidation sequence to form an allylic 1,2-amino alcohol.
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