期刊
ORGANIC LETTERS
卷 11, 期 20, 页码 4668-4670出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901944b
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资金
- DFG
- International Research Training Group [IRTG 1038]
- Volkswagen-Stiftung
- Novartis
- Wacker
This group's recently reported mild zinc-catalyzed enantiospecific sp(3)-sp(3) cross-coupling of lactic acid tert-butylester triflate with Grignard reagents was now applied to an iterative approach in the synthesis of a series of all four possible diastereomers of the shown trideoxypropionate. Oligodeoxypropionate structures are a common motif in a large number of biologically relevant natural products of polyketide origin thus making our approach a versatile tool in their synthesis.
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