期刊
ORGANIC LETTERS
卷 11, 期 3, 页码 761-764出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802803x
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [16380075]
- Grants-in-Aid for Scientific Research [16380075] Funding Source: KAKEN
The first enantioselective total synthesis of aspergillide C, a cytotoxic 14-membered macrolide isolated from the marine-derived fungus Aspergillus ostianus, has been accomplished from a commercially available chiral glycidol derivative by a 12-step sequence involving an expeditious preparation of a cyclic acetal intermediate and a trans-selective Ferrier-type two-carbon homologation reaction.
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