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O-TBS-N-tosylhydroxylamine:: A reagent for facile conversion of alcohols to oximes

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卷 10, 期 11, 页码 2259-2261

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AMER CHEMICAL SOC
DOI: 10.1021/ol800677p

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variety of oximes were synthesized from the corresponding alcohols, alkyl halides, or alkyl sulfonates without using external oxidants. With this simple two-step procedure involving substitution with readily available TsNHOTBS and subsequent treatment with CsF, a range of oximes were prepared including the ones hardly preparable with conventional procedures.

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