期刊
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卷 10, 期 16, 页码 3469-3472出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801247v
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资金
- NIGMS NIH HHS [GM58832] Funding Source: Medline
A series of new pyrrole-based tetraphosphorus ligands were synthesized and used for Rh-catalyzed isomerization-hydroformylation of internal olefins. It was found that the substituents at the 3,3',5,5'-positions of the biphenyl greatly effected the linear selectivity, and the alkyl-substituted tetraphosphorus ligands gave the best results (for 2-octene, n:i up to 207, for 2-hexene, n:i up to 362).
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