期刊
ORGANIC LETTERS
卷 10, 期 17, 页码 3805-3808出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol8014978
关键词
-
资金
- e 21st Century COE (Center of Excellence)
- Ministry of Education, Culture, Sports, Science. and Technology, Japan
Acyloxymethyl radicals were generated from the corresponding iodomethyl esters and successfully underwent addition to the C=N bond of N-Ts, N-PMP, and N-Dpp imines by the action of dimethylzinc or triethylborane. Ethyl acetate, toluene, and benzene as well as dichloromethane were suitable solvents. The utility of acyloxymethyl radicals as a hydroxymethyl anion equivalent was highlighted by the facile hydrolysis of the acyloxy moiety of the adducts to give the corresponding amino alcohol derivatives in good to high yield.
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