期刊
ORGANIC LETTERS
卷 10, 期 20, 页码 4533-4536出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801839w
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资金
- NSERC
- Research Corporation
- Sloan Foundation
- ACS (PRF AC)
- Merck Frosst
- Merck Inc
- Amgen
- Eli Lilly
- Astra Zeneca
- Boehringer Ingelheim
- CH
- ORF
Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro arene relative to the aryl halide. The synthetic utility of this method is demonstrated via rapid synthesis of a Boscalid intermediate.
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