期刊
ORGANIC ELECTRONICS
卷 14, 期 9, 页码 2184-2191出版社
ELSEVIER
DOI: 10.1016/j.orgel.2013.05.017
关键词
Fullerene derivatives; Dibenzosuberane; Morphology; Polymer solar cells
资金
- National High Technology Research and Development Program of China (863 Program) [2011AA050520]
- National Natural Science Foundation of China [61176054]
- Natural Science Foundation of Jiangsu Province of China [SBK201122663]
Two new dibenzosuberane-substituted fullerene derivatives, dibenzosuberane-C-60 monoadduct (DBSCMA) and bis-adduct (DBSCBA) were synthesized using a classical cyclopropanation reaction via a tosylhydrazone route for application as acceptor materials in polymer solar cells (PSCs). DBSCBA shows good solubility in common organic solvents and both derivatives were characterized by (HNMR)-H-1, C-13 NMR, MALD-TOF, elemental analysis and UV-vis absorption measurements. The shift of fullerene energy levels induced by the dibenzosuberane substitution was investigated by using theoretical simulations and ultraviolet photoelectron spectroscopy. Bulk-heterojunction PSCs based on poly (3-hexylthiophene) (P3HT) and dibenzosuberane-C-60 derivatives were fabricated and optimized by adjusting the donor/acceptor ratio and using thermal annealing and solvent additive. The morphologies of the active layers processed under different conditions were also examined by atomic force microscopy. When tested under an illumination of AM 1.5 G at 100 mW/cm(2), the highest power conversion efficiency of the devices using DBSCBA is 3.70% which is superior to that of conventional P3HT: PCBM devices. (C) 2013 Elsevier B.V. All rights reserved.
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