期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 16, 页码 2528-2532出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00215f
关键词
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资金
- ERATO of JST
- Grants-in-Aid for Scientific Research [26288014] Funding Source: KAKEN
We achieved intra- and intermolecular C(sp(3))-H alkoxylation of benzylic positions of heteroaromatic compounds using CuBrn (n = 1, 2)/5,6-dimethylphenanthroline (or 4,7-dimethoxyphen-anthroline) and ((BuO)-Bu-t)(2) as a catalyst and an oxidant, respectively. The reaction proceeded at both terminal and internal benzylic positions of the alkyl groups. The intramolecular alkoxylation was performed on a gram scale.
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