期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 13, 页码 2049-2052出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00018h
关键词
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资金
- National Natural Science Foundation of China
- National Basic Research Program of China (973 Program) [2012CB821600]
- Ministry of Education of China [B06005]
A carboxy-directed asymmetric hydrogenation of alpha-alkyl-alpha-aryl terminal olefins was developed by using a chiral spiro iridium catalyst, providing a highly efficient approach to the compounds with a chiral benzylmethyl center. The carboxy-directed hydrogenation prohibited the isomerization of the terminal olefins, and realized the chemoselective hydrogenation of various dienes. The concise enantioselective syntheses of (S)-curcudiol and (S)-curcumene were achieved by using this catalytic asymmetric hydrogenation as a key step.
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