期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 45, 页码 7859-7868出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41678j
关键词
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资金
- National Natural Science Foundation of China (NSFC) [20972001, 21172002, 21202001]
cis-2,3-Disubstituted cyclopropane 1,1-diesters were found to be much more reactive than their corresponding trans-isomers in the AlCl3-promoted [3 + 2]-annulations with isothiocyanates. The reaction with the cis-cyclopropanes proceeded to completion within minutes, providing a variety of densely substituted diastereomerically pure 2-iminodihydrothiophenes in moderate to excellent yields.
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