期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 27, 页码 4537-4545出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40445e
关键词
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资金
- Department of Science and Technology (DST), Government of India
- Council of Scientific and Industrial Research (CSIR)
A chiral PYBOX-DIPH-Zn(II) catalyzed enantioselective Mukaiyama-Michael reaction of acyclic Ad enol ethers with 2-enoylpyridine N-oxides has been studied in external additive free conditions at ambient temperature. The methodology offers straightforward access to a variety of functionalized chiral 1,5-dicarbonyl compounds, which could easily be elaborated into synthetically viable pyrones via hydrolysis followed by cyclization. A transition state model has been proposed to explain the stereochemical outcome.
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