期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 3, 页码 443-447出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob26950c
关键词
-
资金
- Chinese Academy of Science
- National Sciences Foundation of China [225013]
- Opening Foundation of Zhejiang Provincial Top Key Discipline
We have developed an organocatalytic asymmetric Michael reaction of acylsilane through the selection of acylsilane substrates and organocatalysts, thus creating a rare example of acylsilane alpha-alkylation with a chiral guanidine catalyst, which afforded products in good yields and high stereoselectivity. The corresponding adducts described here have also been demonstrated to be useful in the synthesis of unnatural amino acids and biologically active compounds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据